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Differential Pulse Voltammetry

pypalmsens.DifferentialPulseVoltammetry


              flowchart TD
              pypalmsens.DifferentialPulseVoltammetry[DifferentialPulseVoltammetry]
              pypalmsens._methods.base.BaseTechnique[BaseTechnique]
              pypalmsens._methods.mixins.CurrentRangeMixin[CurrentRangeMixin]
              pypalmsens._methods.mixins.PretreatmentMixin[PretreatmentMixin]
              pypalmsens._methods.mixins.VersusOCPMixin[VersusOCPMixin]
              pypalmsens._methods.mixins.BiPotMixin[BiPotMixin]
              pypalmsens._methods.mixins.PostMeasurementMixin[PostMeasurementMixin]
              pypalmsens._methods.mixins.IrDropCompensationMixin[IrDropCompensationMixin]
              pypalmsens._methods.mixins.EquilibrationTriggersMixin[EquilibrationTriggersMixin]
              pypalmsens._methods.mixins.MeasurementTriggersMixin[MeasurementTriggersMixin]
              pypalmsens._methods.mixins.DataProcessingMixin[DataProcessingMixin]
              pypalmsens._methods.mixins.MultiplexerMixin[MultiplexerMixin]
              pypalmsens._methods.mixins.GeneralMixin[GeneralMixin]
              pypalmsens._methods.base_model.BaseModel[BaseModel]

                              pypalmsens._methods.base.BaseTechnique --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.base.BaseTechnique
                

                pypalmsens._methods.mixins.CurrentRangeMixin --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.mixins.CurrentRangeMixin
                

                pypalmsens._methods.mixins.PretreatmentMixin --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.mixins.PretreatmentMixin
                

                pypalmsens._methods.mixins.VersusOCPMixin --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.mixins.VersusOCPMixin
                

                pypalmsens._methods.mixins.BiPotMixin --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.mixins.BiPotMixin
                

                pypalmsens._methods.mixins.PostMeasurementMixin --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.mixins.PostMeasurementMixin
                

                pypalmsens._methods.mixins.IrDropCompensationMixin --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.mixins.IrDropCompensationMixin
                

                pypalmsens._methods.mixins.EquilibrationTriggersMixin --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.mixins.EquilibrationTriggersMixin
                

                pypalmsens._methods.mixins.MeasurementTriggersMixin --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.mixins.MeasurementTriggersMixin
                

                pypalmsens._methods.mixins.DataProcessingMixin --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.mixins.DataProcessingMixin
                

                pypalmsens._methods.mixins.MultiplexerMixin --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.mixins.MultiplexerMixin
                

                pypalmsens._methods.mixins.GeneralMixin --> pypalmsens.DifferentialPulseVoltammetry
                                pypalmsens._methods.base_model.BaseModel --> pypalmsens._methods.mixins.GeneralMixin
                



              click pypalmsens.DifferentialPulseVoltammetry href "" "pypalmsens.DifferentialPulseVoltammetry"
              click pypalmsens._methods.base.BaseTechnique href "" "pypalmsens._methods.base.BaseTechnique"
              click pypalmsens._methods.mixins.CurrentRangeMixin href "" "pypalmsens._methods.mixins.CurrentRangeMixin"
              click pypalmsens._methods.mixins.PretreatmentMixin href "" "pypalmsens._methods.mixins.PretreatmentMixin"
              click pypalmsens._methods.mixins.VersusOCPMixin href "" "pypalmsens._methods.mixins.VersusOCPMixin"
              click pypalmsens._methods.mixins.BiPotMixin href "" "pypalmsens._methods.mixins.BiPotMixin"
              click pypalmsens._methods.mixins.PostMeasurementMixin href "" "pypalmsens._methods.mixins.PostMeasurementMixin"
              click pypalmsens._methods.mixins.IrDropCompensationMixin href "" "pypalmsens._methods.mixins.IrDropCompensationMixin"
              click pypalmsens._methods.mixins.EquilibrationTriggersMixin href "" "pypalmsens._methods.mixins.EquilibrationTriggersMixin"
              click pypalmsens._methods.mixins.MeasurementTriggersMixin href "" "pypalmsens._methods.mixins.MeasurementTriggersMixin"
              click pypalmsens._methods.mixins.DataProcessingMixin href "" "pypalmsens._methods.mixins.DataProcessingMixin"
              click pypalmsens._methods.mixins.MultiplexerMixin href "" "pypalmsens._methods.mixins.MultiplexerMixin"
              click pypalmsens._methods.mixins.GeneralMixin href "" "pypalmsens._methods.mixins.GeneralMixin"
              click pypalmsens._methods.base_model.BaseModel href "" "pypalmsens._methods.base_model.BaseModel"
            

Create differential pulse voltammetry method parameters.

In Differential Pulse Voltammetry a potential scan is made using pulses with a constant amplitude of pulse_potential superimposed on the dc-potential. The amplitude is mostly in the range of 5 – 50 mV.

Methods:

  • from_dict

    Structure technique instance from dict.

  • from_method_id

    Create new instance of appropriate technique from method ID.

  • to_dict

    Return the technique instance as a new key/value dictionary mapping.

Attributes:

begin_potential class-attribute instance-attribute

begin_potential: float = -0.5

Potential where the scan starts at in V.

bipot class-attribute instance-attribute

bipot: BiPot = Field(default_factory=BiPot)

Set the bipot settings.

current_range class-attribute instance-attribute

current_range: CurrentRange = Field(default_factory=CurrentRange)

Set the autoranging current.

data_processing class-attribute instance-attribute

data_processing: DataProcessing = Field(default_factory=DataProcessing)

Set the data processing settings.

enable_bipot_current class-attribute instance-attribute

enable_bipot_current: bool = False

Enable bipot current.

end_potential class-attribute instance-attribute

end_potential: float = 0.5

Potential where the scan stops at in V.

equilibration_time class-attribute instance-attribute

equilibration_time: float = 0.0

Equilibration time in s.

equilibrion_triggers class-attribute instance-attribute

equilibrion_triggers: EquilibrationTriggers = Field(default_factory=EquilibrationTriggers)

Set the trigger at equilibration settings.

general class-attribute instance-attribute

general: General = Field(default_factory=General)

Sets general/other settings.

ir_drop_compensation class-attribute instance-attribute

ir_drop_compensation: IrDropCompensation = Field(default_factory=IrDropCompensation)

Set the iR drop compensation settings.

measurement_triggers class-attribute instance-attribute

measurement_triggers: MeasurementTriggers = Field(default_factory=MeasurementTriggers)

Set the trigger at measurement settings.

multiplexer class-attribute instance-attribute

multiplexer: Multiplexer = Field(default_factory=Multiplexer)

Set the multiplexer settings.

post_measurement class-attribute instance-attribute

post_measurement: PostMeasurement = Field(default_factory=PostMeasurement)

Set the post measurement settings.

pretreatment class-attribute instance-attribute

pretreatment: Pretreatment = Field(default_factory=Pretreatment)

Set the pretreatment settings.

pulse_potential class-attribute instance-attribute

pulse_potential: float = 0.05

Pulse potential height in V.

pulse_time class-attribute instance-attribute

pulse_time: float = 0.01

Pulse time in s.

This duration needs to be set shorter than 0.5 * interval time where the interval time is equal to potential_step / scan_rate.

record_auxiliary_input class-attribute instance-attribute

record_auxiliary_input: bool = False

Record auxiliary input.

record_cell_potential class-attribute instance-attribute

record_cell_potential: bool = False

Record cell potential.

Counter electrode vs ground.

record_we_potential class-attribute instance-attribute

record_we_potential: bool = False

Record applied working electrode potential.

Reference electrode vs ground.

scan_rate class-attribute instance-attribute

scan_rate: float = 1.0

Scan rate (potential/time) in V/s.

The maximum scan rate depends on the value of step_potential step and pulse_time. The scan rate must be < (step_potential / pulse_time).

step_potential class-attribute instance-attribute

step_potential: float = 0.1

Potential step size in V.

versus_ocp class-attribute instance-attribute

versus_ocp: VersusOCP = Field(default_factory=VersusOCP)

Set the versus OCP settings.

from_dict classmethod

from_dict(obj: dict[str, Any]) -> BaseTechnique

Structure technique instance from dict.

Opposite of .to_dict()

Source code in src/pypalmsens/_methods/base.py
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@classmethod
def from_dict(cls, obj: dict[str, Any]) -> BaseTechnique:
    """Structure technique instance from dict.

    Opposite of `.to_dict()`"""
    return cls.model_validate(obj)

from_method_id classmethod

from_method_id(id: str) -> BaseTechnique

Create new instance of appropriate technique from method ID.

Source code in src/pypalmsens/_methods/base.py
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@classmethod
def from_method_id(cls, id: str) -> BaseTechnique:
    """Create new instance of appropriate technique from method ID."""
    new = cls._registry[id]
    return new()

to_dict

to_dict() -> dict[str, Any]

Return the technique instance as a new key/value dictionary mapping.

Source code in src/pypalmsens/_methods/base.py
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def to_dict(self) -> dict[str, Any]:
    """Return the technique instance as a new key/value dictionary mapping."""
    return self.model_dump()